I know this may sound a bit silly but my LO has been doing something similar (having previously gone to sleep within less than 15mins of being put in bed) but he isn't potty trained so he would be shouting asking us for a drink, but then didn't want it once we were there and instead wanted to talk.
What we have been doing the past week, and it has worked every single time (there's no longer any getting out of bed, no shouting for Mummy/Daddy/a drink and he is asleep within 15mins of us leaving the room) is once I read stories, brush his teeth and he says night, night he climbs into bed and lies down then I sit down on the floor beside his bed and we talk for around 5 minutes about what he has done during the day, and what we are going to do the next day. He seems to need those few minutes of getting everything out of his head before he can go to sleep. My H says he is just like me as I have to talk before going to sleep too.

He remembers what we have talked about too, as for instance, he came running through this morning asking for 'type type choo choo plee Daddy' (he wanted to watch Thomas songs on H's ipad) and I had said he could do that today, as he had wanted it when it was bedtime but I had said no and that he could see them in the morning. So at 6:28am we were subjected to him bouncing on our bed whilst listening to Thomas.