I was going to say sunlight too but unfortunately we haven't had much of that in this country recently! If I can't hang things out in the sun I use vanish (the oxi action powder) or sometimes salt as that is quite good for drawing stains out.
I soak things in Biotex, you can buy it in supermarkets in the washing powder aisle. I put some in a bucket and then soak clothes etc overnight and then wash them as normal. I have never had a stain that Biotex doesn't fix. Or you can use your usual washing powder/liquid, put quite alot in a bucket and then soak overnight.
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