I love temping and I'm sure over time you will too! It does take a bit of practice to get used to. I believe fertility friend has some really good resources to get you set up and it's super easy chart online - I like using my cell phone. I keep my thermometer on the bedside table and take my temp when I wake in the morning. Some people stress about the exact time of day that you take it, but I'm a shift worker with sleep patterns all over the place and I haven't had any odd charts due to the varied times I take my temp. As long as you take your temp after 3 or so hours of solid sleep. Keep in mind that certain things will change your temp - such as drinking too much the night prior, I find wheat affects my temp... everyone is different and it'll just take time to figure out your body.
Hope that helps! Best of luck!